When was thomson model created
In , Ernest Rutherford, a former student of J. Thomson, proved Thomson's plum pudding structure incorrect. Rutherford with the assistance of Ernest Marsden and Hans Geiger performed a series of experiments using alpha particles. Rutherford aimed alpha particles at solid substances such as gold foil and recorded the location of the alpha particle "strikes" on a fluorescent screen as they passed through the foil. Plum pudding is an English dessert similar to a blueberry muffin.
The positive matter was thought to be jelly- like or a thick soup. The electrons were somewhat mobile. As they got closer to the outer portion of the atom, the positive charge in the region was greater than the neighboring negative charges and the electron would be pulled back more toward the center region of the atom.
However, this model of the atom soon gave way to a new model developed by New Zealander Ernest Rutherford about five years later. Thomson did still receive many honors during his lifetime, including being awarded the Nobel Prize in Physics in and a knighthood in Use the link below to answer the following questions:.
Skip to main content. Atomic Structure. Search for:. What is this model airplane composed of? Figure 1. Summary A model gives an idea of what something looks like, but is not the real thing. In this model, what is the dough? What was the major purpose of the plum pudding model?
How is this model different from modern modes of the atom? The spectra of hydrogen-like ions are similar to hydrogen, but shifted to higher energy by the greater attractive force between the electron and nucleus. The tacit assumption here is that the nucleus is more massive than the stationary electron, and the electron orbits about it. This is consistent with the planetary model of the atom. Equating these:.
This means that it takes energy to pull the orbiting electron away from the proton. Using this equation, the energy of a photon emitted by a hydrogen atom is given by the difference of two hydrogen energy levels:. Fig 1 : A schematic of the hydrogen spectrum shows several series named for those who contributed most to their determination.
Part of the Balmer series is in the visible spectrum, while the Lyman series is entirely in the UV, and the Paschen series and others are in the IR. Values of nf and ni are shown for some of the lines. Atomic and molecular emission and absorption spectra have been known for over a century to be discrete or quantized. Maxwell and others had realized that there must be a connection between the spectrum of an atom and its structure, something like the resonant frequencies of musical instruments.
But, despite years of efforts by many great minds, no one had a workable theory. It was a running joke that any theory of atomic and molecular spectra could be destroyed by throwing a book of data at it, so complex were the spectra. In some cases, it had been possible to devise formulas that described the emission spectra. As you might expect, the simplest atom—hydrogen, with its single electron—has a relatively simple spectrum. The hydrogen spectrum had been observed in the infrared IR , visible, and ultraviolet UV , and several series of spectral lines had been observed.
The observed hydrogen-spectrum wavelengths can be calculated using the following formula:. These series are named after early researchers who studied them in particular depth. The Paschen series and all the rest are entirely IR.
Electron transitions and their resulting wavelengths for hydrogen. While the formula in the wavelengths equation was just a recipe designed to fit data and was not based on physical principles, it did imply a deeper meaning. Bohr was the first to comprehend the deeper meaning. Again, we see the interplay between experiment and theory in physics. Experimentally, the spectra were well established, an equation was found to fit the experimental data, but the theoretical foundation was missing.
The wave-like properties of matter were subsequently confirmed by observations of electron interference when scattered from crystals.
Electrons can exist only in locations where they interfere constructively. How does this affect electrons in atomic orbits? When an electron is bound to an atom, its wavelength must fit into a small space, something like a standing wave on a string. Waves on a String : a Waves on a string have a wavelength related to the length of the string, allowing them to interfere constructively. Allowed orbits are those in which an electron constructively interferes with itself. Not all orbits produce constructive interference and thus only certain orbits are allowed i.
As previously stated, Bohr was forced to hypothesize this rule for allowed orbits. We now realize this as the condition for constructive interference of an electron in a circular orbit. Accordingly, a new kind of mechanics, quantum mechanics, was proposed in The new theory was proposed by Werner Heisenberg. This described electrons that were constrained to move about the nucleus of a hydrogen-like atom by being trapped by the potential of the positive nuclear charge.
By the early 20th century, research into the interaction of X-rays with matter was well underway. Although classical electromagnetism predicted that the wavelength of scattered rays should be equal to the initial wavelength, multiple experiments had found that the wavelength of the scattered rays was longer corresponding to lower energy than the initial wavelength.
In his paper, Compton derived the mathematical relationship between the shift in wavelength and the scattering angle of the X-rays by assuming that each scattered X-ray photon interacted with only one electron. His paper concludes by reporting on experiments which verified his derived relation:. Because the mass-energy and momentum of a system must both be conserved, it is not generally possible for the electron simply to move in the direction of the incident photon.
The interaction between electrons and high energy photons comparable to the rest energy of the electron, keV results in the electron being given part of the energy making it recoil , and a photon containing the remaining energy being emitted in a different direction from the original, so that the overall momentum of the system is conserved. If the scattered photon still has enough energy left, the Compton scattering process may be repeated. In this scenario, the electron is treated as free or loosely bound.
Photons with an energy of this order of magnitude are in the x-ray range of the electromagnetic radiation spectrum. Therefore, you can say that Compton effects with electrons occur with x-ray photons. If the photon is of lower energy, but still has sufficient energy in general a few eV to a few keV, corresponding to visible light through soft X-rays , it can eject an electron from its host atom entirely a process known as the photoelectric effect , instead of undergoing Compton scattering.
Higher energy photons 1. In a previous Atom on X-rays, we have seen that there are two processes by which x-rays are produced in the anode of an x-ray tube. In one process, the deceleration of electrons produces x-rays, and these x-rays are called Bremsstrahlung , or braking radiation. The second process is atomic in nature and produces characteristic x-rays, so called because they are characteristic of the anode material.
The x-ray spectrum in is typical of what is produced by an x-ray tube, showing a broad curve of Bremsstrahlung radiation with characteristic x-ray peaks on it. The smooth part of the spectrum is bremsstrahlung radiation, while the peaks are characteristic of the anode material. A different anode material would have characteristic x-ray peaks at different frequencies.
Since x-ray photons are very energetic, they have relatively short wavelengths. For example, the Thus, typical x-ray photons act like rays when they encounter macroscopic objects, like teeth, and produce sharp shadows. However, since atoms and atomic structures have a typical size on the order of 0.
The process is called x-ray diffraction because it involves the diffraction and interference of x-rays to produce patterns that can be analyzed for information about the structures that scattered the x-rays. When x-ray are incident on an atom, they make the electronic cloud move as an electromagnetic wave. The movement of these charges re-radiate waves with the same frequency.
This is called Rayleigh Scattering, which you should remember from a previous atom. A similar thing happens when neutron waves from the nuclei scatter from interaction with an unpaired electron.
These re-emitted wave fields interfere with each other either constructively or destructively, and produce a diffraction pattern that is captured by a sensor or film. This is called the Braggs diffraction, and is the basis for x-ray diffraction.
Perhaps the most famous example of x-ray diffraction is the discovery of the double-helix structure of DNA in Using x-ray diffraction data, researchers were able to discern the structure of DNA shows a diffraction pattern produced by the scattering of x-rays from a crystal of protein. This process is known as x-ray crystallography because of the information it can yield about crystal structure. Not only do x-rays confirm the size and shape of atoms, they also give information on the atomic arrangements in materials.
For example, current research in high-temperature superconductors involves complex materials whose lattice arrangements are crucial to obtaining a superconducting material. These can be studied using x-ray crystallography. X-Ray Diffraction : X-ray diffraction from the crystal of a protein, hen egg lysozyme, produced this interference pattern. Analysis of the pattern yields information about the structure of the protein.
The Compton Effect is the phenomenon of the decrease in energy of photon when scattered by a free charged particle. Compton scattering is an inelastic scattering of a photon by a free charged particle usually an electron.
It results in a decrease in energy increase in wavelength of the photon which may be an X-ray or gamma ray photon , called the Compton Effect. Part of the energy of the photon is transferred to the scattering electron. Inverse Compton scattering also exists, and happens when a charged particle transfers part of its energy to a photon. Scattering in the Compton Effect : The Compton Effect is the name given to the scattering of a photon by an electron.
Energy and momentum are conserved, resulting in a reduction of both for the scattered photon. Studying this effect, Compton verified that photons have momentum.
Compton scattering is an example of inelastic scattering because the wavelength of the scattered light is different from the incident radiation. Still, the origin of the effect can be considered as an elastic collision between a photon and an electron. The amount of change in the wavelength is called the Compton shift. Although nuclear Compton scattering exists, Compton scattering usually refers to the interaction involving only the electrons of an atom.
The Compton effect is important because it demonstrates that light cannot be explained purely as a wave phenomenon. Thomson scattering, the classical theory of an electromagnetic wave scattered by charged particles, cannot explain low intensity shifts in wavelength: classically, light of sufficient intensity for the electric field to accelerate a charged particle to a relativistic speed will cause radiation-pressure recoil and an associated Doppler shift of the scattered light.
0コメント